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Nanotubes Enhance Ionisation Sensor

Researchers at New York’s Rensselaer Polytechnic Institute (RPI) have created minaturised gas ionisation sensors based on multi-wall carbon nanotube (MWNT) elements (Nature, July 10, 2003).
Researchers at New York's Rensselaer Polytechnic Institute (RPI) have created minaturised gas ionisation sensors based on multi-wall carbon nanotube (MWNT) elements (Nature, July 10, 2003).


Ionisation sensors provide fingerprints of distinct gases but are normally bulky and consume large amounts of power at high voltages. The MWNT-based sensors use the sharp tips of the tubes to generate very high electric ionisation fields at relatively low voltages. The MWNT film was created by chemical vapour deposition (CVD) on a silicon dioxide substrate.


The high electric fields at the tube tips hasten the breakdown process. The precise breakdown voltage provides a fingerprint for the particular gas. The discharge current is determined by the gas concentration. Because the technique does not involve adsorption/desorption of gases, the sensor displays a fast response.


The first test in air with an anode-cathode separation of 150microns generated a 460microA discharge at 346V. Without the nanotubes, the same structure generates a 69microA current at 960V. Further tests of the nanotube sensor showed detection capability for helium, argon, nitrogen, oxygen, carbon dioxide and ammonia.


The team also investigated the use of the sensor for gas chromatography. The researchers believe that with an appropriate design, analytes in low ppm range (around 25ppm) could be detected. This could lead to the development of field-portable gas chromatographs for use in emergencies and counter-terrorism activities.



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