News Article
Electron microscopy enters the pico metre scale
Jülich scientists are pioneers of ultra high resolution electron
microscopy.
Jülich scientists have succeeded
in precisely measuring atomic spacings down to a few pico metres
using new methods in ultra high resolution electron microscopy. This
makes it possible to find out decisive parameters determining the
physical properties of materials directly on an atomic level in a
microscope. Knut Urban from Forschungszentrum Jülich, a member
of the Helmholtz Association, reports on this in the latest issue (25
July) of the scientific journal 'Science'.
Progress in research in the area of physics is very frequently connected to an increase in the accuracy of measurements, which help researchers to track natural phenomena. With the aid of new methods in electron optics, researchers were able to microscopically measure atomic displacements precisely to a few pico metres. A pico metre corresponds to a billionth of a millimetre a distance that is one hundred times smaller than the diameter of an atom. This is one of the highlights that Knut Urban, director of the Ernst Ruska Centre in Jülich, reports on in "Science" as part of a review of ten years of electron microscopy with aberration corrected lenses.
Jülich scientists investigated, for example, the configuration of atoms in orthogonal grain boundaries of the oxide superconductor YBa2Cu3O7. These atoms mark the boundary between two areas of the crystalline material with atomic structures that are tilted at an angle of exactly 90° to each other. From microscopic images taken under different conditions, the physicists succeeded in using computers to calculate the quantum mechanical wave function of the electrons, which served as a basis for determining the exact position of the atoms. In doing so, it became apparent that the relatively heavy atomic species barium, copper and yttrium are systematically displaced a few pico metres from their ideal position in the grain boundary and that the lighter oxygen atoms follow this displacement. This provides an explanation for the attenuation of superconducting properties, which can be observed when electric current flows over such a grain boundary. This phenomenon is undesired if the superconductor is intended to be used for a loss-free current transport. However, it is useful for the construction of so called SQUIDs (superconducting quantum interference devices), which exploit the magnetic field dependency of this disturbance to measure smallest magnetic fields, for example, to measure brain waves (magnetoencephalography).
Displacements of a few pico metres decide on a whole number of physical properties, which are of eminent importance for technology. Another example is the ferro-electricity of titanate materials. Here, the electrical charges of the individual types of atoms inside the building blocks of crystals, the unit cells, cannot fully compensate for each other as they are not arranged in the necessary symmetry. Therefore, electric dipoles are formed inside the unit cells, which add up over a larger crystal area to form the so called polarisation. This is used to write information bits. An example is PbZr0.2Ti0.8O3 which is used in chip cards for data storage. With the aid of new electron optical methods, atomic displacements can be measured atom by atom thus making it possible to determine local polarisation for the first time. Knut Urban explains: "This is the beginning of a new physics of materials which enables researchers to determine physical parameters and properties in the nano range through highly precise measurements of the atomic spacings. This will also provide clues on how these properties may be manipulated in order to gain new functions and better functional performance."
Progress in research in the area of physics is very frequently connected to an increase in the accuracy of measurements, which help researchers to track natural phenomena. With the aid of new methods in electron optics, researchers were able to microscopically measure atomic displacements precisely to a few pico metres. A pico metre corresponds to a billionth of a millimetre a distance that is one hundred times smaller than the diameter of an atom. This is one of the highlights that Knut Urban, director of the Ernst Ruska Centre in Jülich, reports on in "Science" as part of a review of ten years of electron microscopy with aberration corrected lenses.
Jülich scientists investigated, for example, the configuration of atoms in orthogonal grain boundaries of the oxide superconductor YBa2Cu3O7. These atoms mark the boundary between two areas of the crystalline material with atomic structures that are tilted at an angle of exactly 90° to each other. From microscopic images taken under different conditions, the physicists succeeded in using computers to calculate the quantum mechanical wave function of the electrons, which served as a basis for determining the exact position of the atoms. In doing so, it became apparent that the relatively heavy atomic species barium, copper and yttrium are systematically displaced a few pico metres from their ideal position in the grain boundary and that the lighter oxygen atoms follow this displacement. This provides an explanation for the attenuation of superconducting properties, which can be observed when electric current flows over such a grain boundary. This phenomenon is undesired if the superconductor is intended to be used for a loss-free current transport. However, it is useful for the construction of so called SQUIDs (superconducting quantum interference devices), which exploit the magnetic field dependency of this disturbance to measure smallest magnetic fields, for example, to measure brain waves (magnetoencephalography).
Displacements of a few pico metres decide on a whole number of physical properties, which are of eminent importance for technology. Another example is the ferro-electricity of titanate materials. Here, the electrical charges of the individual types of atoms inside the building blocks of crystals, the unit cells, cannot fully compensate for each other as they are not arranged in the necessary symmetry. Therefore, electric dipoles are formed inside the unit cells, which add up over a larger crystal area to form the so called polarisation. This is used to write information bits. An example is PbZr0.2Ti0.8O3 which is used in chip cards for data storage. With the aid of new electron optical methods, atomic displacements can be measured atom by atom thus making it possible to determine local polarisation for the first time. Knut Urban explains: "This is the beginning of a new physics of materials which enables researchers to determine physical parameters and properties in the nano range through highly precise measurements of the atomic spacings. This will also provide clues on how these properties may be manipulated in order to gain new functions and better functional performance."
