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Silicon on germanium nanowires enrich lithium-ion batteries
The University of California San Diego and National Labs have coated germanium nanowires with silicon to stop nearly all surface diffusion of lithium ions into the nanowires
New research led by an electrical engineer at the University of California, San Diego is aimed at improving lithium-ion batteries through possible new electrode architectures with precise nano-scale designs. Researchers created nanowires that block diffusion of lithium across their silicon surface and promote layer-by-layer axial lithiation of the nanowire's germanium core. Shadi Dayeh, a professor in the Department of Electrical and Computer Engineering at the UC San Diego Jacobs School of Engineering, explains that this work could lead to "an effective way to tailor volume expansion of lithium ion battery electrodes which could potentially minimise their cracking, improve their durability, and perhaps influence how one could think about different electrode architectures." The research was recently published in the journal Nano Letters. By coating germanium nanowires with silicon, the researchers stopped nearly all surface diffusion of lithium ions into the nanowires. Instead, lithium diffusion, known as lithiation, occurred layer by layer along the axis of the nanowire. This is in contrast to lithiation from the surface of nanowires not covered with silicon. "These results demonstrate for the first time that interface and bandgap engineering of electrochemical reactions can be utilised to control the nanoscale ionic transport / insertion paths and thus may be a new tool to define the electrochemical reactions in Li-ion batteries," the researchers write in their Nano Letters paper. This work builds on research demonstrating excellent control over germanium / silicon (Ge/Si) heterostructuring, which Dayeh and colleagues recently published as a cover article in Applied Physics Letters and a cover letter in the journal Nano Letters. Dayeh grew the nanowires during his time as a postdoctoral researcher at Los Alamos National Laboratory (LANL). Lithiation experiments were performed by two postdoctoral researchers from Sandia National Laboratories, Yang Liu and Xiaohua Liu, and Dayeh's researchers working at LANL. Dayeh formulated the mechanism and performed the analysis and simulations after joining the faculty of the Electrical and Computer Engineering Department at the UC San Diego Jacobs School of Engineering. Tailoring Lithiation Behavior by Interface and Bandgap Engineering at the Nanoscale Further details of this work have been published in the paper,"Tailoring Lithiation Behavior by Interface and Bandgap Engineering at the Nanoscale," by Yang Liu et al in Nano Letters. DOI: 10.1021/nl402754Funding sources for this research includes Nanostructures for Electrical Energy Storage (NEES), an Energy Frontier Research Centre (EFRC) funded by the U.S. Department of Energy, Los Alamos National Laboratory, Sandia National Laboratories, and UC San Diego.
